Preheat the oven to 325 degrees, grease (with vegetable shortening) and flour three 8x2 inch round pans. We also like to line the bottom of pans with circles of parchment paper.
In a medium bowl, add the flour, cocoa powder, baking powder, baking soda, and salt. Whisk to blend and set aside
In another bowl, add the buttermilk, oil and vanilla. Set aside
In the bowl of your mixer, add the softened butter and mix at medium speed until smooth. Gradually add the sugar and continue to mix on medium speed 3 to 5 minutes until lightened in color and fluffy.
Add the eggs one at a time, mixing after each one until the yellow of the yolk is blended.
With the mixer on low speed, alternately, add the flour mixture and buttermilk mixture, beginning and ending with the dry ingredients (3 additions of dry and 2 of wet). Mix just until blended.
Continuing at low speed, slowly add the ¾ cup of very hot coffee, mixing until batter is blended and smooth.
Divide the cake batter between the three 8 inch cake pans. Bake at 325 degrees for 25 to 30 minutes or until a toothpick inserted in the center comes out clean or with just a few crumbs attached. Let cool 5 to 10 minutes and turn out of pan.